Thuanvo,
I have the 534-SS’s as side surrounds and would highly recommend them. The 534-SS’s blend well with wall mounting and I think they would also work well for rear surround.
The sound effects you can get with the 534’s and their Bi/Dipole switching provide a lot of adjustment at the speaker and the AVR to customize the sound.
I am not a big fan in any way of In-Wall or In-Ceiling speakers for reasons that Daryl sited and the fact that once they are installed, there is no room for experimentation in positioning unless you are happy with cutting a new hole and patching the previous.
Like Daryl, I also have the 422’s as rear surround but in a 7.1 setup and they work well in various sound fields.
Jack